Structure of some simple molecules

CH4
methane

Methane
NH3
Ammonia

Ammonia
H2O
Water

Water
H3CCH3
Ethane

Ethane
H2CCH2
Ethene

Ethene
HCCH
Ethyne

Ethyne
cis- ClHCCHCl
cis-dichloroethene

cis-dichloroethene
trans- ClHCCHCl
trans-dichloroethene

trans-dichloroethene
CHClFBr stereos
CHClFBr stereos

stereo isomers
SF6
sulfur hexafluoride

SF6 - sp3d2 - octahedron - non-polar
PF5
phosphorous pentafluoride

PF5 - sp3d - trigonal bipyramid - non-polar
SF5Cl
sulfur pentafluoride monochloride

SF5Cl - sp3d2 - octahedral - polar
SF5-ion*
sulfur pentafluoride ion

SF5- - sp3d2 - square pyramid - polar
IF3
iodine trifluoride ion

IF3 - sp3d - T-shaped - polar
SF42-ion*
sulfur tetrafluoride ion

SF42- - sp3d2 - square planar - non-polar

*The van der Waal radius for the neutral molecule is used here for the ions.