1. Determine the oxidation numbers of all atoms and tag the atoms that change oxidation numbers | |||
2. Split those tagged atoms out into the two half (cell) reactions | |||
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3. Balance the atom which changes oxidation number. | |||
4. Add |
on the left for the reduction | electrons equal to the change in oxidation number (each) times the number of atoms that change oxidation number (total.) | |
on the right for oxidation | |||
5. Balance the spectator ions such as Cl-, OH-, H+, etc. | |||
6. Balance the oxygen by: |
in acid: adding 1 H2O for each O and 2 H+ on the other side. | ||
In base: adding 2 OH- for each O and 1 H2O on the other side. | |||
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7. Add the two half reactions together such that the electrons cancel. (Find a common factor.) |
Here is a repeat of the lazy person's guide to oxidation numbers of atoms in compounds and ions.:
Name(acid) ion:
acid: |
hypo...ite
hypo...ous |
...ite
...ous |
...ate
...ic |
per...ate
per...ic |
|
chlor | ClO- | ClO2- | ClO3- | ClO4- | |
brom | BrO- | BrO2- | BrO3- | BrO4- | |
iod | IO- | IO2- | IO3- | IO4- | |
sulf(ur) | SO22- | SO32- | SO42- | ||
nitr | NO2- | NO3- | |||
phosph(or) | PO23- | PO33- | PO43- | ||
carbon | CO32- | ||||
chrom | CrO42- | ||||
dichrom | Cr2O72- | ||||
mangan | MnO4- |
Others:
hydroxide: OH- | hydronium: H3O+ | ammonium: NH4+ |
Some special polyions for which O does not have an oxidation
number of -2
peroxide O22- | superoxide O2- |